Battery Electrolytes & Separators
Electrolytes and separators are critical enablers of lithium-ion and next-generation battery performance. The electrolyte provides the medium for ion transport between the anode and cathode, while the separator ensures electrical isolation while allowing ionic conduction. Together, they determine key performance factors such as safety, cycle life, charging speed, and energy density.
Battery electrolytes
Electrolytes in EV batteries are typically liquid formulations of lithium salts dissolved in organic solvents, with additives to enhance stability, conductivity, and safety. Solid-state and gel electrolytes are in development to improve safety and enable higher energy densities.
| Electrolyte Type | Composition | Advantages | Constraints |
|---|---|---|---|
| Liquid Electrolytes | Lithium hexafluorophosphate (LiPF6) in carbonate solvents | Mature, high ionic conductivity, widely adopted | Flammable; thermal runaway risk; limited voltage window |
| Gel/Polymer Electrolytes | Polyethylene oxide (PEO), PVDF-based gels | Better mechanical stability; improved safety vs liquids | Lower ionic conductivity; scaling challenges |
| Solid-State Electrolytes | Sulfide, oxide, or polymer-based solids | Non-flammable; enables lithium-metal anodes; high energy density | Manufacturing complexity; interfacial resistance; cost |
Electrolyte vendor list
| Manufacturer | Product | Location |
|---|---|---|
| Ampcera | Solid state electrolyte | Tucson, AZ |
| Aqualith Advanced Materials | Aqueous electrolyte | College Park, MD |
| BASF | Solvents | Geismar, LA |
| BrightVolt | Polymer Electrolyte | Newberry , IN |
| Current Chemicals | Liquid electrolyte | Cleveland, OH |
| Enchem America | Liquid electrolyte | Commerce, GA |
| Honeywell International | Liquid electrolyte | Buffalo, NY |
| Huntsman Petrochemical | Solvents | Conroe, TX |
| Koura - Orbia | LiFP6 | St. Gabriel, LA |
| Mitsubishi Chemical America | Liquid electrolyte | Memphis, TN |
| Solvay Specialty Polymers | Liquid electrolyte | Augusta, GA |
| Soulbrain MI | Liquid electrolyte | Northville, MI |
| South 8 Technologies | Liquefied gas electrolyte | San Diego, CA |
Battery separators
The separator is a microporous polymer membrane that prevents direct contact between anode and cathode while allowing lithium ions to pass through. Separator design directly impacts battery safety, internal resistance, and cycle life.
| Separator Type | Material | Advantages | Constraints |
|---|---|---|---|
| Polyolefin Separators | Polyethylene (PE), polypropylene (PP) | Low cost; established supply chain | Limited thermal stability; shrinkage risk under heat |
| Ceramic-Coated Separators | Polymer base with alumina or ceramic coatings | Improved thermal resistance; enhanced safety | Higher cost; added processing steps |
| Next-Gen Solid Separators | Glass, oxide, or composite structures | Non-flammable; supports solid-state designs | Not yet commercially scaled; manufacturing challenges |
Separator vendor list
| Manufacturer | Product | Location |
|---|---|---|
| Celgard | Separators | Charlotte, NC |
| Celgard | Separators | Concord, NC |
| Entek | Separators | Lebanon, OR |
| Microvast | Separators | Clarksville, TN |
Electrode support materials
Beyond electrolytes and separators, EV batteries rely on a range of auxiliary materials that stabilize electrodes, enhance conductivity, and maintain mechanical integrity. These include additives that extend cycle life, adhesives that secure cell components, and binders that hold active materials together on current collectors. Though used in small amounts, they are essential for reliable high-volume cell manufacturing.
| Material Type | Examples | Function | Constraints |
|---|---|---|---|
| Conductive Additives | Carbon black, carbon nanotubes, graphene | Improve electronic conductivity of electrode mixes | Cost and dispersion challenges; quality consistency |
| Electrolyte Additives | Vinylene carbonate (VC), fluoroethylene carbonate (FEC) | Form stable SEI layers, reduce gas generation, improve cycle life | Precise formulation control needed; adds cost |
| Binders | Polyvinylidene fluoride (PVDF), water-based SBR/CMC | Hold active particles to current collectors, enable mechanical integrity | Solvent recovery requirements (NMP for PVDF); sustainability concerns |
| Adhesives & Sealants | Epoxies, polyurethanes, silicone-based adhesives | Bonding of separator, electrodes, and structural pack elements | Thermal expansion mismatch; chemical stability under cycling |
| Coatings | Al2O3, TiO2, thin ceramic or polymer films | Surface modification of separators/electrodes to improve stability | Added processing steps; trade-off with cost per kWh |
While these materials make up only a few percent of total cell mass, they are crucial enablers of high-energy-density cells and safer fast-charging. Supply is dominated by specialty chemical firms in Japan, Korea, China, and increasingly Europe, making sourcing and formulation IP a competitive differentiator for cell makers.
Support materials vendor list
| Manufacturer | Product | Location |
|---|---|---|
| Arkema | Adhesives | Wauwatosa, WI |
| Arkema | Binders | Calvert City, KY |
| Black Diamond Structures | Additives | Austin, TX |
| Cabot | Additives | Pampa, TX |
| Daikin America | Additives | Decatur, AL |
| DuPont | Additives | Wilmington, DE |
| Halocarbon | Additives | Beech Island, SC |
| LI-CAP Technologies | Other | Sacramento, CA |
| Parker LORD | Adhesives | Saegertown, PA |
| PPG | Other | Pittsburgh, PA |
| The Chemours Company | Binders | Washington, WV |
| Volexion | Graphene coating | Evanston, IL |
Why They Matter
Electrolytes and separators are critical determinants of EV battery safety and reliability. Improvements in these materials directly impact charging speeds, range, and cycle life. Failures in either component can cause short circuits, thermal runaway, or catastrophic pack failures.
Supply Chain & Risks
Electrolyte and separator production is concentrated among specialized chemical and materials companies, many in China, Japan, and South Korea. Risks include dependency on fluorochemicals (for LiPF6), rising demand outpacing separator film capacity, and cost pressures from safety-enhanced designs. Automakers are increasingly partnering with material suppliers to secure allocations and accelerate next-gen R&D (e.g., solid-state). Recycling and recovery of solvents and separator films is limited today but expected to grow in importance.
Market Outlook & Adoption (Ranked)
| Rank | Technology | Adoption Drivers | Constraints |
|---|---|---|---|
| 1 | Liquid Electrolytes + Polyolefin Separators | Mature, cost-effective, scaled supply chain | Safety limitations; thermal runaway risk |
| 2 | Ceramic-Coated Separators + Additive-Rich Electrolytes | Improved safety, higher temperature tolerance, faster charging | Higher cost; capacity expansions needed |
| 3 | Solid-State Electrolytes & Separators | Game-changing safety and energy density potential | Not yet commercial; manufacturing scale-up challenges |
