Battery Supply Chain > Electrolytes & Separators
Battery Electrolytes & Separators
Electrolytes and separators form the ionic transport and safety backbone of lithium-ion batteries. While they represent a smaller fraction of cell mass and cost than electrodes, they are decisive for power capability, fast charging, low-temperature performance, cycle life, and safety. These components are tightly co-optimized with cathode and anode materials, which makes them chemistry- and customer-specific rather than fully interchangeable commodities.
Why electrolytes and separators matter
Electrolytes and separators control how lithium ions move between electrodes and how failure modes are mitigated. Small formulation or material changes can materially affect cell performance and safety margins.
- Electrolytes determine ionic conductivity, voltage stability, and temperature range.
- Separators prevent short circuits while allowing ion transport.
- Both components strongly influence fast-charging behavior and thermal stability.
Battery electrolytes
Electrolytes in EV batteries are typically liquid formulations of lithium salts dissolved in organic solvents, with additives to enhance stability, conductivity, and safety. Solid-state and gel electrolytes are in development to improve safety and enable higher energy densities.
| Electrolyte Type | Composition | Advantages | Constraints |
|---|---|---|---|
| Liquid Electrolytes | Lithium hexafluorophosphate (LiPF6) in carbonate solvents | Mature, high ionic conductivity, widely adopted | Flammable; thermal runaway risk; limited voltage window |
| Gel/Polymer Electrolytes | Polyethylene oxide (PEO), PVDF-based gels | Better mechanical stability; improved safety vs liquids | Lower ionic conductivity; scaling challenges |
| Solid-State Electrolytes | Sulfide, oxide, or polymer-based solids | Non-flammable; enables lithium-metal anodes; high energy density | Manufacturing complexity; interfacial resistance; cost |
Electrolyte performance tradeoffs
- High ionic conductivity vs chemical stability.
- Fast charging vs lithium plating risk.
- Low-temperature performance vs high-temperature durability.
Next-generation electrolytes
Next-generation electrolytes aim to extend voltage window, improve fast-charging performance, and enhance thermal stability while remaining compatible with existing lithium-ion manufacturing lines. Most near-term advances build on liquid electrolyte systems rather than replacing them entirely.
- High-voltage electrolytes — optimized salt and additive systems that support cathodes operating above ~4.3–4.4 V without rapid decomposition
- Fast-charge formulations — additive packages that suppress lithium plating and stabilize the SEI during high-rate charging
- Low-temperature electrolytes — solvent blends designed to maintain ionic conductivity and power delivery in cold environments
Beyond conventional liquids, hybrid approaches are under active development but remain largely pre-commercial for high-volume EV use.
- Gel and semi-solid electrolytes — improve safety and leakage resistance while retaining liquid-like ion transport
- Solid-state-adjacent electrolytes — intermediate systems that bridge current liquid electrolytes and fully solid-state designs
In the near to medium term, electrolyte innovation is expected to be incremental and chemistry-specific, with adoption driven by compatibility with existing cell lines, qualification speed, and total system cost rather than step-change material replacement.
Battery separators
The separator is a microporous polymer membrane that prevents direct contact between anode and cathode while allowing lithium ions to pass through. Separator design directly impacts battery safety, internal resistance, and cycle life.
| Separator Type | Material | Advantages | Constraints |
|---|---|---|---|
| Polyolefin Separators | Polyethylene (PE), polypropylene (PP) | Low cost; established supply chain | Limited thermal stability; shrinkage risk under heat |
| Ceramic-Coated Separators | Polymer base with alumina or ceramic coatings | Improved thermal resistance; enhanced safety | Higher cost; added processing steps |
| Next-Gen Solid Separators | Glass, oxide, or composite structures | Non-flammable; supports solid-state designs | Not yet commercially scaled; manufacturing challenges |
Separator safety role
- Thermal shutdown: pore collapse at elevated temperature can halt ion transport.
- Mechanical integrity: resistance to puncture and dendrite penetration.
- Dimensional stability: critical under high-rate and elevated-temperature operation.
Battery-grade requirements
Electrolytes and separators are qualified as part of a complete cell system rather than in isolation.
- Ultra-low moisture content to prevent electrolyte decomposition.
- Consistent composition and thickness control.
- Long-term chemical compatibility with electrode materials.
Electrolyte manufacturers and plants
The table below lists representative electrolyte production facilities supplying lithium-ion battery manufacturers.
| Company / Operator | Facility | Location | Primary products |
|---|---|---|---|
| Capchem | Electrolyte Manufacturing Base | Huizhou, Guangdong, China | Lithium-ion battery electrolytes |
| Guangzhou Tinci Materials | Electrolyte Production Facilities | China (multiple) | Electrolytes and additives |
| Mitsubishi Chemical | Battery Electrolyte Plants | Japan | Electrolytes |
| BASF | Electrolyte Production Lines | Europe | Battery electrolytes |
U.S. electrolyte OEMs and plants
| Manufacturer | Product | Location |
|---|---|---|
| Ampcera | Solid state electrolyte | Tucson, AZ |
| Aqualith Advanced Materials | Aqueous electrolyte | College Park, MD |
| BASF | Solvents | Geismar, LA |
| BrightVolt | Polymer Electrolyte | Newberry , IN |
| Current Chemicals | Liquid electrolyte | Cleveland, OH |
| Enchem America | Liquid electrolyte | Commerce, GA |
| Honeywell International | Liquid electrolyte | Buffalo, NY |
| Huntsman Petrochemical | Solvents | Conroe, TX |
| Koura - Orbia | LiFP6 | St. Gabriel, LA |
| Mitsubishi Chemical America | Liquid electrolyte | Memphis, TN |
| Solvay Specialty Polymers | Liquid electrolyte | Augusta, GA |
| Soulbrain MI | Liquid electrolyte | Northville, MI |
| South 8 Technologies | Liquefied gas electrolyte | San Diego, CA |
Separator manufacturers and plants
The table below lists representative separator production facilities worldwide supplying lithium-ion battery manufacturers.
| Company / Operator | Facility | Location | Primary products |
|---|---|---|---|
| Asahi Kasei | Hipore Separator Plants | Japan / United States | Lithium-ion battery separators |
| SK IE Technology | Separator Manufacturing Plants | South Korea / Europe | Battery separators |
| Toray Industries | Separator Production Facilities | Japan | Battery separators |
| Entek | Separator Manufacturing Plant | Indiana, United States | Battery separators |
U.S. separator OEMs and plants
| Manufacturer | Product | Location |
|---|---|---|
| Celgard | Separators | Charlotte, NC |
| Celgard | Separators | Concord, NC |
| Entek | Separators | Lebanon, OR |
| Microvast | Separators | Clarksville, TN |
Battery support materials
Beyond electrolytes and separators, EV batteries rely on a range of auxiliary materials that stabilize electrodes, enhance conductivity, and maintain mechanical integrity. These include additives that extend cycle life, adhesives that secure cell components, and binders that hold active materials together on current collectors. Though used in small amounts, they are essential for reliable high-volume cell manufacturing.
| Material Type | Examples | Function | Constraints |
|---|---|---|---|
| Conductive Additives | Carbon black, carbon nanotubes, graphene | Improve electronic conductivity of electrode mixes | Cost and dispersion challenges; quality consistency |
| Electrolyte Additives | Vinylene carbonate (VC), fluoroethylene carbonate (FEC) | Form stable SEI layers, reduce gas generation, improve cycle life | Precise formulation control needed; adds cost |
| Binders | Polyvinylidene fluoride (PVDF), water-based SBR/CMC | Hold active particles to current collectors, enable mechanical integrity | Solvent recovery requirements (NMP for PVDF); sustainability concerns |
| Adhesives & Sealants | Epoxies, polyurethanes, silicone-based adhesives | Bonding of separator, electrodes, and structural pack elements | Thermal expansion mismatch; chemical stability under cycling |
| Coatings | Al2O3, TiO2, thin ceramic or polymer films | Surface modification of separators/electrodes to improve stability | Added processing steps; trade-off with cost per kWh |
While these materials make up only a few percent of total cell mass, they are crucial enablers of high-energy-density cells and safer fast-charging. Supply is dominated by specialty chemical firms in Japan, Korea, China, and increasingly Europe, making sourcing and formulation IP a competitive differentiator for cell makers.
Battery support materials OEMs and plants
| Manufacturer | Product | Location |
|---|---|---|
| Arkema | Adhesives | Wauwatosa, WI |
| Arkema | Binders | Calvert City, KY |
| Black Diamond Structures | Additives | Austin, TX |
| Cabot | Additives | Pampa, TX |
| Daikin America | Additives | Decatur, AL |
| DuPont | Additives | Wilmington, DE |
| Halocarbon | Additives | Beech Island, SC |
| LI-CAP Technologies | Other | Sacramento, CA |
| Parker LORD | Adhesives | Saegertown, PA |
| PPG | Other | Pittsburgh, PA |
| The Chemours Company | Binders | Washington, WV |
| Volexion | Graphene coating | Evanston, IL |
Supply chain & outlook
Electrolyte and separator production is concentrated among specialized chemical and materials companies, many in China, Japan, and South Korea. Risks include dependency on fluorochemicals (for LiPF6), rising demand outpacing separator film capacity, and cost pressures from safety-enhanced designs. Automakers are increasingly partnering with material suppliers to secure allocations and accelerate next-gen R&D (e.g., solid-state). Recycling and recovery of solvents and separator films is limited today but expected to grow in importance.
| Rank | Technology | Adoption Drivers | Constraints |
|---|---|---|---|
| 1 | Liquid Electrolytes + Polyolefin Separators | Mature, cost-effective, scaled supply chain | Safety limitations; thermal runaway risk |
| 2 | Ceramic-Coated Separators + Additive-Rich Electrolytes | Improved safety, higher temperature tolerance, faster charging | Higher cost; capacity expansions needed |
| 3 | Solid-State Electrolytes & Separators | Game-changing safety and energy density potential | Not yet commercial; manufacturing scale-up challenges |
